I've been looking all around to find a decent review that shows me how good is the quality of Spotify's "High quality" streaming. No luck, so I'll do one.
CD RIP (flac)
This is the spectrum and wave of the original, 1996 CD version:
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320kbps MP3 from CD RIP by ffmpeg
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CD"

Spotify high quality (desktop) streaming
( Recorded with audio-recorder[^3] into flac. )
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quality"
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high quality"
Spotify normal quality (desktop) streaming
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quality"

Conclusions: high quality is still not CD, but is far ahead of the 320k MP3 output of ffmpeg.
(Oh, by the way: this entry was written by Peter Molnar, and originally posted on petermolnar dot net.)